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Metal-ion-linked molecular multilayers on metal oxide surfaces are promising for applications ranging from solar energy conversion to sensing. Most of these applications rely on energy and electron transfer between layers/molecules which can be envisioned to occur via intra-assembly (IA; between metal-ion-linked molecules) and interlayer (IL; between separate layers of nonlinked molecules) processes. Here, we describe our effort to differentiate between IL and IA energy transfer using a bilayer composed of ZrO2, a phosphonated anthracene derivative (A), a zinc(II) linking ion, and a Pt(II)porphyrin (P). Both time-resolved emission and transient absorption measurements show no impact of diluting the anthracene layer with a spectroscopically inert spacer on the rate of 1A* to P and 3P* to A, singlet, and triplet energy transfer, respectively. These results indicate that energy transfer within the metal-ion-linked assembly (i.e., ZrO2-A–Zn-P) is more rapid than with an adjacent, nonlinked A molecule, even for a P derivative capable of laying down on the surface. These insights are an important step toward structural design principles maximizing the efficiency/rate of energy transfer in multilayer assemblies.